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Surface tension and mechanical properties in polyolefin composites
Author(s) -
Pukánszky Béla,
Fekete Erika,
Tüdós Ferenc
Publication year - 1989
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19890280112
Subject(s) - polyolefin , composite material , materials science , interphase , ultimate tensile strength , surface tension , stearic acid , filler (materials) , polymer , yield (engineering) , polystyrene , modulus , genetics , physics , layer (electronics) , quantum mechanics , biology
Polyolefin composites were prepared with CaCO 3 fillers of different specific surface area. The fillers were surface treated with stearic acid between 0 and 100% surface coverage. As an effect of the treatment, surface tension of the fillers and also polymer/filler interaction decreased. The relation between interfacial interaction and mechanical properties of the composites was analysed by the equation developed earlier to describe the composition dependence of the tensile yield stress. The characteristics of the interphase were calculated, its yield stress decreases and thickness increases with increasing surface coverage. Reversible work of adhesion can be successfully related to the tensile yield stress, but a more complicated correlation exists between the thickness of the interphase and the strength of the interaction than assumed earlier. Other mechanical properties also change with the surface treatment; modulus and strength decrease and extensibility increases with decreasing polymer/filler interaction.