Determination of kinetic constants for bulk polymerization of octyl acrylate at different temperatures | Zendy

Katime Issa A. | Zendy; Nuño T. | Zendy

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Determination of kinetic constants for bulk polymerization of octyl acrylate at different temperatures

Author(s) -

Katime Issa A.,

Nuño T.

Publication year - 1988

Publication title -

makromolekulare chemie. macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 0258-0322

DOI - 10.1002/masy.19880200115

Subject(s) - polymerization , activation energy , kinetics , acrylate , kinetic energy , thermodynamics , reaction rate constant , polymer chemistry , chemistry , order of reaction , atmospheric temperature range , range (aeronautics) , materials science , copolymer , organic chemistry , polymer , physics , composite material , quantum mechanics

The bulk self‐initiated polymerization kinetics, assuming complete conversion of the octyl acrylate was determined by DTA in the temperature range 463‐493 K. Likewise, the overall activation energy, E A , and the polymerization enthalpies involved in the process have been calculated, as well as the overall rate constants and the reaction order.

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