Ring opening polymerization of cycloolefins by means of metathesis catalyst: Kinetic and thermodynamic effects on the product distribution | Zendy

Höcker Hartwig | Zendy

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Ring opening polymerization of cycloolefins by means of metathesis catalyst: Kinetic and thermodynamic effects on the product distribution

Author(s) -

Höcker Hartwig

Publication year - 1986

Publication title -

makromolekulare chemie. macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 0258-0322

DOI - 10.1002/masy.19860060108

Subject(s) - metathesis , polymerization , catalysis , product distribution , chemistry , ring (chemistry) , polymer chemistry , ring opening metathesis polymerisation , product (mathematics) , kinetic energy , photochemistry , organic chemistry , polymer , physics , geometry , mathematics , quantum mechanics

The metathesis reaction of cycloolefins is a ring‐opening polymerization with a metallacyclobutane system as the key intermediate. A kinetically and a thermodynamically controlled regime of the reaction clearly can be distinguished, the latter being characterized by a ring‐chain equilibrium.

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