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Synthesis of polyheterocycles on the basis of poly‐functional monomers and study of their characteristics
Author(s) -
Zhubanov B. A.
Publication year - 1986
Publication title -
makromolekulare chemie. macromolecular symposia
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 0.257
H-Index - 76
eISSN - 1521-3900
pISSN - 0258-0322
DOI - 10.1002/masy.19860040117
Subject(s) - alicyclic compound , condensation polymer , monomer , trimellitic anhydride , polymer , polymer chemistry , polymerization , materials science , functional polymers , polyamide , organic chemistry , chemistry
Application of polyfunctional monomers in the course of polycondensation allows to synthesize different types of polymers using different activity of functional groups. It is possible in this case to vary to a large extent the characteristics of the obtained polymers. The presence of functional groups of different activity in one monomer also allows to modify it by introduction of new fragments for subsequent use in polycondensation or polymerization reactions. The abovementioned is confirmed by the example of using trimellitic anhydride and a number of alicyclic tetracarbonic dianhydrides. Trimellitic anhydride is directly used for synthesis of polymers and also modified for preparation of new derivatives. The perspective of using alicyclic tetracarbonic dianhydrides for synthesis of heterocycles has been shown. Varying the monomer nature and conditions of a polycondensation reaction, polymers with different specific characteristics have been obtained: heat‐resistant, high‐ and low‐fusible, soluble, incombustible, film‐forming, fiber‐forming, binding for glass‐plastics.