Addition reactions of carbocations with alkenes: Studies on the mechanism of carbocationic polymerization | Zendy

Mayr Herbert | Zendy; Pock Rudolf | Zendy; Schneider Reinhard | Zendy

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Addition reactions of carbocations with alkenes: Studies on the mechanism of carbocationic polymerization

Author(s) -

Mayr Herbert,

Pock Rudolf,

Schneider Reinhard

Publication year - 1986

Publication title -

makromolekulare chemie. macromolecular symposia

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 0.257

H-Index - 76

eISSN - 1521-3900

pISSN - 0258-0322

DOI - 10.1002/masy.19860030104

Subject(s) - carbocation , chemistry , cationic polymerization , polymerization , alkene , alkyl , reaction mechanism , photochemistry , isobutylene , lewis acids and bases , polymer chemistry , organic chemistry , catalysis , copolymer , polymer

In certain cases, Lewis acid catalyzed addition reactions of alkyl halides with alkenes terminate at the 1:1 product stage. This telomerization reaction has been employed to study the efficiency of initiating systems of carbocationic polymerization and the relative reactivities of alkenes towards carbenium ions. A direct determination of addition rate constants is possible in some cases.

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