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Gas‐phase ion thermochemistry in organometallic systems
Author(s) -
Operti Lorenza,
Rabezzana Roberto
Publication year - 2003
Publication title -
mass spectrometry reviews
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 2.035
H-Index - 126
eISSN - 1098-2787
pISSN - 0277-7037
DOI - 10.1002/mas.10065
Subject(s) - thermochemistry , chemistry , bond energy , gas phase , reactivity (psychology) , ligand (biochemistry) , ion , scope (computer science) , organometallic chemistry , binding energy , group 2 organometallic chemistry , computational chemistry , metal , bond order , chemical physics , bond length , atomic physics , crystallography , molecule , organic chemistry , crystal structure , medicine , biochemistry , physics , alternative medicine , computer science , programming language , receptor , pathology
I. Introduction 408 II. Techniques Employed to Measure Binding Energies 409A. Continuous‐Ejection Technique (CE) 409B. Equilibrium Measurements 409C. Kinetic Method 410D. Radiative Association (RA) Kinetics Method 410E. Threshold‐CID Experiments 410F. Zero‐Pressure Thermal Radiation‐Induced Dissociation Technique (ZTRID) 411 III. Metal Ion—Ligand Binding Energies 411A. Lithium 411B. Sodium 412C. Magnesium 413D. Aluminum 414E. Silicon 414F. Potassium 414G. Calcium, Strontium 415H. Scandium 415I. Titanium 415J. Vanadium 415K. Chromium 416L. Manganese 416M. Iron 416N. Cobalt, Nickel 419O. Copper 419P. Zinc 421Q. Rubidium, Cesium 421R. Molibdenum, Tungsten 423S. Silver, Cadmium 423T. Platinum 425 References 425This review represents a general overview on the determination of bond energies in gas‐phase organometallic systems. The paper focuses on articles published in the last 7 years, whose main scope was to experimentally measure metal ion–ligand binding energies. Therefore, studies of reactivity and characterization of ion complexes are not included, even if some of them display bond energies among the data measured. Bond energies are presented according to the metal ion complexed, in increasing order of atomic number. Periodic trends of binding energies and correlations among the various ligand are discussed. A brief summary of the most used techniques specifically devoted to gather bond energies is also provided. © 2003 Wiley Periodicals, Inc., Mass Spec Rev 22:407–428, 2003; Published online in Wiley InterScience ( www.interscience.wiley.com ). DOI 10.1002/mas.10065