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Rate‐Limited Reaction in TEMPO/Laccase/O 2 Oxidation of Cellulose
Author(s) -
Jiang Jie,
Chen Huangjingyi,
Yu Juan,
Liu Liang,
Fan Yimin,
Saito Tsuguyuki,
Isogai Akira
Publication year - 2021
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.202170009
Subject(s) - cellulose , laccase , redox , nanofiber , environmentally friendly , reaction rate , chemistry , reaction mechanism , polymer chemistry , chemical engineering , organic chemistry , materials science , catalysis , nanotechnology , enzyme , biology , ecology , engineering
Back Cover : In article number 2000501 by Yimin Fan and co‐workers, the TEMPO/laccase/O 2 system is an environmentally friendly option for cellulose oxidation to prepare nanofibers. The whole oxidation is divided into separated reactions to calculate each reaction rate at different pH values. The rate‐limited reaction in this system at pH 4.5 is cellulose oxidation by TEMPO+.