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From Dimeric to Octameric Metallo‐Supramolecular Macrocycles Based on Sterically Congested Ligand–assisted Self‐Assembly with Zn(II), Cd(II), and Fe(II)
Author(s) -
Guan Shengwen,
Yu Hao,
Zhang Zhe,
Jiang Xin,
Shi Junjuan,
Lu Tong,
Wang Chunyu,
Wang Pingshan,
Wang Ming
Publication year - 2020
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.202070054
Subject(s) - terpyridine , supramolecular chemistry , steric effects , crystallography , chemistry , ligand (biochemistry) , self assembly , zipper , stereochemistry , rhombus , supramolecular assembly , crystal structure , metal , organic chemistry , computer science , biochemistry , receptor , geometry , mathematics , algorithm
Inside Front Cover : In article number 2000095 by Ming Wang and coworkers, the synthesis and self‐assembly of two sterically congested terpyridinebased ligands with asymmetrically contiguous terpyridine units is reported. The terpyridine units in these ligands show a selective coordination ability and can preferentially form a rhombus‐like intermediate to assist the formation of the final dimeric to octameric metallo‐supramolecular macrocycles.