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Direct Synthesis of Chain‐end‐functionalized Poly(3‐hexylthiophene) without Protecting Groups Using a Zincate Complex
Author(s) -
Inagaki Shin,
Yamamoto Takuya,
Higashihara Tomoya
Publication year - 2020
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.202070027
Subject(s) - zincate , condensation polymer , polymer chemistry , chain (unit) , negishi coupling , end group , polyester , catalysis , polymer , materials science , chemistry , organic chemistry , copolymer , zinc , physics , astronomy
Back Cover : In article 2000148, Tomoya Higashihara and co‐workers synthesize chain‐end‐functionalized poly(3‐hexylthiophene)s (P3HTs) with benzyl alcohol, phenol, and benzoic acid groups via Negishi catalyst‐transfer polycondensation using a zincate complex. The chain‐end‐functionalized P3HTs have controlled number‐average molecular weights and high chain‐end functionality.