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Rotaxane‐Based Difunctional Nitrile N ‐Oxide Crosslinker: Synthesis and Direct Introduction of Movable Crosslinking Points into Ethylene‐Propylene‐Butadiene Monomer (EPDM) Rubber
Author(s) -
Sogawa Hiromitsu,
Tsutsuba Toyokazu,
Sakiyama Naoto,
Ikeda Tatsuhito,
Takata Toshikazu
Publication year - 2021
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.202000639
Subject(s) - monomer , materials science , nitrile , rotaxane , ethylene oxide , polymer , polymer chemistry , natural rubber , propylene oxide , ultimate tensile strength , ethylene , chemical engineering , copolymer , composite material , catalysis , chemistry , molecule , organic chemistry , supramolecular chemistry , engineering
Incorporation of rotaxane scaffolds into the crosslinking points of polymer networks significantly affects their rheological and mechanical properties. The present study involves the synthesis of a new rotaxane‐type crosslinker containing nitrile N ‐oxide functional groups on both the axle and wheel components. The prepared crosslinker is highly reactive; however, it can be isolated and applied in the crosslinking reaction of a commercially important polymer, namely ethylene‐propylene‐butadiene monomer rubber (EPDM), in the absence of additives and catalysts. Tensile tests reveal that compared to a network containing conventional crosslinking points, both breaking strength and strain of the network structure prepared herein are improved due to the incorporation of movable crosslinking points. The synthesized network structure also exhibits five times higher fracture energy. The developed post‐crosslinking methodology for the direct introduction of movable crosslinking points into pre‐formed polymers will be valuable in the production of rotaxane materials for various applications.