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Controls and Effects of Monomer Junctions and Sequences in Curable and Degradable Polyarylate Containing Acrylate Moieties
Author(s) -
Kohsaka Yasuhiro,
Nagai Koki
Publication year - 2021
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.202000570
Subject(s) - acryloyl chloride , monomer , acrylate , polymer chemistry , polymerization , crystallinity , polymer , materials science , ether , bisphenol a , acrylate polymer , bisphenol , chemistry , organic chemistry , epoxy , composite material
In contrast to solution polymerization, interfacial polymerization of α‐(chloromethyl)acryloyl chloride and bisphenol Z results in fast esterification and slow ether formation, affording regulated monomer junctions. The controlled structure increases the crystallinity of the resulting polymers. In addition, terpolymerization with dicarboxylic acid chloride results in controlled monomer sequences with uniformly distributed acrylate moieties, leading to efficient curability.