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Phase Transition Behaviors and Nanoscale Film Morphologies of Poly(δ‐valerolactone) Axles Bearing Movable and Fixed Rotaxane Wheels
Author(s) -
Ree Brian J.,
Aoki Daisuke,
Kim Jehan,
Satoh Toshifumi,
Takata Toshikazu,
Ree Moonhor
Publication year - 2019
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201900334
Subject(s) - rotaxane , materials science , axle , polymer , amorphous solid , nanoscopic scale , composite material , lamellar structure , phase (matter) , crystallography , crystal structure , chemistry , nanotechnology , structural engineering , supramolecular chemistry , organic chemistry , engineering
In this study, poly(δ‐valerolactone) (PVL) axles bearing movable and fixed dibenzo‐24‐crown‐8‐ether wheels ( rot ‐M and rot ‐F) are investigated for the first time in the terms of phase transition and nanoscale film morphology: PVL‐ rot‐ M and PVL‐ rot ‐F. Interestingly, the PVL axles reveal a strong tendency to form a horizontal lamellar structure with three different rotational crystal lattice domains in nanoscale films. The morphological structural parameters are discernibly varied by the movable and fixed rotaxane wheels. In particular, the rot ‐M wheel tends to be populated in both the interfacial and amorphous layers. The rot ‐M wheel is found to significantly influence the phase transition characteristics of the PVL axle because of its movability along the polymer backbone chain. In contrast, the rot ‐F wheel tends to be more localized in the interfacial layer rather than in the amorphous layer because of its immovability constrained at the polymer chain end. The rot ‐F wheel causes severe thermal instability in the PVL axle, which can be attributed mainly to the presence of its counter anion (PF 6 − ).