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TAD Click Chemistry on Aliphatic Polycarbonates: A First Step Toward Tailor‐Made Materials
Author(s) -
Baroni Alexandra,
Vlaminck Laetitia,
Mespouille Laetitia,
Prez Filip Du,
Delbosc Nicolas,
Blankert Bertrand
Publication year - 2019
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201800743
Subject(s) - click chemistry , polymerization , copolymer , biocompatible material , polymer chemistry , chemistry , conjugated system , combinatorial chemistry , materials science , polymer , polymer science , organic chemistry , biomedical engineering , medicine
For the first time, the effectiveness of triazolinedione (TAD) click chemistry onto aliphatic polycarbonates (APC) is demonstrated. Statistic copolymers carrying click‐reactive conjugated diene (in a ratio of 10%) are synthesized via organocatalyzed ring‐opening polymerization. The highly efficient click reaction of TADs carrying simple butyl and phenyl functions are confirmed by 1 H‐NMR and DSC. Network formation using a bivalent TAD is also performed and simply characterized by DSC. This post‐polymerization functionalization of biocompatible and biodegradable APC pave the way to easy and versatile “on‐demand” materials design.