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Redox‐Responsive Polymer with Self‐Immolative Linkers for the Release of Payloads
Author(s) -
Iamsaard Supitchaya,
Seidi Farzad,
Dararataruphorn,
Crespy Daniel
Publication year - 2018
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201800071
Subject(s) - redox , polymer , covalent bond , combinatorial chemistry , chemistry , corrosion , electrochemistry , nanotechnology , side chain , materials science , polymer chemistry , organic chemistry , electrode
Previous couplings of corrosion inhibitors to redox‐responsive polymers via covalent bonding suffer from several drawbacks. It is presented here novel redox‐responsive polymer‐corrosion inhibitor conjugates that contain self‐immolative linkers in their side chains. Very fast redox‐induced release of tryptamine, a drug and a corrosion inhibitor, is observed after applying a reductive trigger.