Premium
Synthesis of Two Well‐Defined Quadruple‐Stranded Copolymers having Two Kinds of Backbones by Postpolymerization of a Helical Template Polymer
Author(s) -
Zang Yu,
Aoki Toshiki,
Tanagi Hiroyoki,
Matsui Kana,
Teraguchi Masahiro,
Kaneko Takashi,
Ma Liqun,
Jia Hongge,
Shinohara Kenichi
Publication year - 2018
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201700556
Subject(s) - copolymer , monomer , polymer , stacking , polymer chemistry , materials science , supramolecular chemistry , self assembly , chain (unit) , polymer science , side chain , crystallography , chemistry , nanotechnology , organic chemistry , crystal structure , physics , astronomy , composite material
Abstract A brand new, soluble quadruple‐stranded copolymer is synthesized by using a self‐template polymer from a new monomer. In addition, another very unique quadruple‐stranded copolymer having a π−π stacking supramolecular polymer main chain is synthesized by selective photocyclic aromatization of the quadruple‐stranded copolymer. The two quadruple‐stranded copolymers gave self‐standing membranes.