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Lowering the Healing Temperature of Photoswitchable Dynamic Covalent Polymer Networks
Author(s) -
Fuhrmann Anne,
Broi Kevin,
Hecht Stefan
Publication year - 2018
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201700376
Subject(s) - covalent bond , polymer , materials science , coating , self healing , robustness (evolution) , nanotechnology , computer science , composite material , chemistry , organic chemistry , medicine , biochemistry , alternative medicine , pathology , gene
To reduce the environmental footprint of the modern society, it is desirable to elongate the lifetime of consumer products, for example by implementing healable coatings and protective layers. However, since most healing processes carried out by heat or light suffer from material degradation, improving the robustness and integrity of healable materials is of tremendous importance to prolong their lifetime. In recent work, a prototype is created of a dynamic covalent polymer network, whose thermal healing ability can be switched “on” and “off” by light to provide a means to locally control repair of a damaged coating. Based on the initial concept, herein a new set of difunctional crosslinkers and linear polymers of various compositions is presented to form dynamic covalent polymer networks, in which the barrier for the retro Diels–Alder decrosslinking reaction is decreased. The approach results in lower healing temperatures and thus a longer lifetime of the material.