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Porous Poly(Ionic Liquid) Membranes as Efficient and Recyclable Absorbents for Heavy Metal Ions
Author(s) -
Ren Yongyuan,
Zhang Jiandong,
Guo Jiangna,
Chen Fei,
Yan Feng
Publication year - 2017
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201700151
Subject(s) - membrane , ionic liquid , metal ions in aqueous solution , absorption (acoustics) , metal , polymer , ionic bonding , materials science , imidazole , chemical engineering , monomer , polymer chemistry , ion , chemistry , organic chemistry , composite material , catalysis , biochemistry , engineering
Heavy metal ion pollution has become a serious environmental problem. Herein, this study reports the synthesis of poly(ionic liquid) (PIL) membranes via in situ photo‐crosslinking of vinyl imidazole with both hydrophilic and hydrophobic ionic liquid monomers. The resultant amphiphilic polymer membranes are porous and exhibit high absorption capacity of metal ions (including Hg 2+ , Pb 2+ , Cu 2+ , Cd 2+ , and Zn 2+ ) in both high (1000 mg L −1 ) and low (10 mg L −1 ) concentration metal ion solutions. These metal ionic absorption membranes are easily regenerated in acid solution and can be reused without significant decreases of absorption capacity after many cycles. These PIL membranes may have potential applications as eco‐friendly and safe heavy metal ion removal materials.