Macromol. Rapid Commun. 12/2016 | Zendy

Saito Yusuke | Zendy; Nakata Norio | Zendy; Ishii Akihiko | Zendy

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Macromol. Rapid Commun. 12/2016

Author(s) -

Saito Yusuke,

Nakata Norio,

Ishii Akihiko

Publication year - 2016

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.201670051

Subject(s) - polymerization , tacticity , silylation , polymer , polymer chemistry , zirconium , macromolecule , stereoselectivity , sequence (biology) , chemistry , materials science , catalysis , organic chemistry , biochemistry

Back Cover: Highly isospecific polymerization of silyl‐protected ω‐alkenols, using a combination of [OSSO]‐type bis(phenolato) dichloro zirconium(IV) complex and dMAO as the precatalyst and the activator, respectively, is established. This method represents the first example for a stereoselective polymerization of polar functional α‐olefins ([ mmmm ] > 95%). Subsequently, the obtained terminal siloxy‐substituted isotactic polymer could be readily transformed by a macromolecular desilylation/acetylation reaction sequence to afford the corresponding terminal acetyl‐enriched polymer. Further details can be found in the article by Y. Saito, N. Nakata,* and A. Ishii* on page 969.

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