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Macromol. Rapid Commun. 1/2016
Author(s) -
Suga Takeo,
Aoki Kohei,
Yashiro Toshiaki,
Nishide Hiroyuki
Publication year - 2016
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201670004
Subject(s) - copolymer , polymer chemistry , polymerization , block (permutation group theory) , raft , cover (algebra) , materials science , conductivity , chemistry , composite material , polymer , mathematics , mechanical engineering , engineering , geometry
Back Cover: RAFT polymerization yields reactive block copolymers bearing the pentafluorophenyl ester (PFPA) group, and subsequent Click amidation using 2,2,6,6‐tetramethylpiperidine‐ N ‐oxyl‐ (TEMPO‐) and imidazolium‐functionalized primary amines produces the corresponding functional block copolymers, leading to installation of statistical radical and ionic‐ sites into the PFPA segment. The monolayered thin film devices fabricated using the obtained block copolymers exhibit repeatable switching (memory) characteristic of electric conductivity (on/off ratio > 103) under a bias voltage. Further details can be found in the article by T. Suga,* K. Aoki, T. Yashiro, and H. Nishide* on page 53.