Macromol. Rapid Commun. 5/2015 | Zendy

Mineart Kenneth P. | Zendy; Jiang Xi | Zendy; Jinnai Hiroshi | Zendy; Takahara Atsushi | Zendy; Spontak Richard J. | Zendy

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Macromol. Rapid Commun. 5/2015

Author(s) -

Mineart Kenneth P.,

Jiang Xi,

Jinnai Hiroshi,

Takahara Atsushi,

Spontak Richard J.

Publication year - 2015

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.201570018

Subject(s) - cyclohexane , solvent , transmission electron microscopy , tetrahydrofuran , materials science , casting , polymer chemistry , ionic bonding , hexagonal crystal system , copolymer , chemical engineering , composite material , polymer , crystallography , chemistry , nanotechnology , organic chemistry , ion , engineering

Front Cover: The morphology of a sulfonated pentablock ionomer is shown to depend sensitively on the casting solvent(s) used in deposition. Images obtained from transmission electron microscopy and microtomography reveal that casting from a nonpolar solvent, cyclohexane, produces discrete ionic microdomains embedded in a nonpolar matrix. Alternatively, casting from a relatively polar solvent, tetrahydrofuran, results in the coexistence of alternating lamellae and nonpolar cylinders arranged on a hexagonal lattice in a sulfonated matrix. Further details can be found in the article by K. P. Mineart, X. Jiang, H. Jinnai, A. Takahara, and R. J. Spontak* on page 432.

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