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Living ROMP Synthesis and Redox Properties of Diblock Ferrocene/Cobalticenium Copolymers
Author(s) -
Ciganda Roberto,
Gu Haibin,
Castel Patricia,
Zhao Penxiang,
Ruiz Jaime,
Hernández Ricardo,
Astruc Didier
Publication year - 2016
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201500566
Subject(s) - romp , copolymer , ferrocene , monomer , metathesis , polymerization , redox , polymer chemistry , materials science , electrochemistry , ring opening metathesis polymerisation , chemistry , electrode , polymer , composite material , metallurgy
Using the third‐generation Grubbs catalyst, the living ring‐opening metathesis polymerization of ferrocene/cobalticenium copolymers is conducted with theoretical numbers of 25 monomer units for each block, and their redox and electrochemical properties allow using the Bard–Anson electrochemical method to determine the number of metallocenyl units in each block.