Coordination RC 6 H 4 S(CH 2 ) 8 SC 6 H 4 R/(CuI)  n   Polymers (R ( n ) = H (4); Me (8)): An Innocent Methyl Group that Makes the Difference | Zendy

Harvey Pierre D. | Zendy; Bonnot Antoine | Zendy; Lapprand Antony | Zendy; Strohmann Carsten | Zendy; Knorr Michael | Zendy

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Coordination RC 6 H 4 S(CH 2 ) 8 SC 6 H 4 R/(CuI) n Polymers (R ( n ) = H (4); Me (8)): An Innocent Methyl Group that Makes the Difference

Author(s) -

Harvey Pierre D.,

Bonnot Antoine,

Lapprand Antony,

Strohmann Carsten,

Knorr Michael

Publication year - 2015

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.201400659

Subject(s) - luminescence , polymer , crystallography , cubane , combinatorics , chemistry , physics , materials science , crystal structure , mathematics , optics , nuclear magnetic resonance

Under identical conditions, CuI reacts with PhS(CH 2 ) 8 SPh and p ‐TolS(CH 2 ) 8 STol‐ p affording, respectively, a luminescent 1D coordination polymer [Cu 4 I 4 {μ 2 ‐PhS(CH 2 ) 8 SPh} 2 ] n ( 1 ) and an unprecedented 2D network [Cu 8 I 8 {μ 2 ‐ p ‐TolS(CH 2 ) 8 STol‐ p } 3 (MeCN) 2 ] n ( 2 ), which incorporate closed‐cubane Cu 4 I 4 and octanuclear Cu 8 I 8 clusters of as connecting nodes. Their thermal and photophysical properties exhibit notable differences.

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