Glucose Oxidase and Glucose for Redox‐Initiating the Free Radical Copolymerization of  N ‐(ferrocenoylmethyl)acrylamide in Aqueous Cyclodextrin Solution | Zendy

Szillat Florian | Zendy; Shamout Fadi | Zendy; Ritter Helmut | Zendy

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Glucose Oxidase and Glucose for Redox‐Initiating the Free Radical Copolymerization of N ‐(ferrocenoylmethyl)acrylamide in Aqueous Cyclodextrin Solution

Author(s) -

Szillat Florian,

Shamout Fadi,

Ritter Helmut

Publication year - 2015

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.201400612

Subject(s) - comonomer , copolymer , glucose oxidase , acrylamide , aqueous solution , cyclodextrin , redox , chemistry , polymer chemistry , ferrocene , polymer , organic chemistry , electrochemistry , enzyme , electrode

The glucose oxidase and glucose mediated formation of amphipilic copolymers of N ‐(ferrocenoylmethyl)acrylamide (NFMA) and N,N ‐diethylacrylamide (DEA) in aqueous cyclodextrin solution is presented. Thereby, NFMA is not only a comonomer but also part of the redox initiation system. The obtained copolymers contain NFMA units between 1 and 10 mol%. The molecular masses of the copolymers are dependent on the ferrocene content, whereupon molecular weights between 38 000 and 71 000 g mol −1 are achieved.

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