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Supramolecular Assembly of C 3 Peptidic Molecules into Helical Polymers
Author(s) -
Dai Yutang,
Zhao Xin,
Su Xinyan,
Li Guangyu,
Zhang Afang
Publication year - 2014
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201400158
Subject(s) - supramolecular chemistry , polymer , molecule , materials science , supramolecular polymers , nanotechnology , supramolecular assembly , polymer science , chemistry , polymer chemistry , organic chemistry , composite material
Self‐assembly of C 3 discotic molecules bearing dipeptide pendants into helical supramolecular polymers is investigated. The dipeptides are constituted from glycine and alanine with altered sequence, aiming at modulating the steric hindrance and examining the steric effects on the assembly. This steric hindrance effect is further illustrated with a dipeptide formed from glycine and valine, which carries a much larger isopropyl side unit. Their supramolecular polymerization is examined in various organic solvents and at different temperatures. The assembly morphology is directly visualized with atomic force microscopy. It is found that small changes in the dipeptide motifs in combination with solvent structure and the solution concentrations lead to different expression of the supramolecular assembly.