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Formation of a Copillar[5]arene‐Based Supramolecular Polymer in Solution and in the Solid State
Author(s) -
Gao Lingyan,
Zhang Zibin,
Dong Shengyi,
Xue Min
Publication year - 2014
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201400048
Subject(s) - monomer , supramolecular chemistry , polymerization , polymer , polymer chemistry , supramolecular polymers , solid state , materials science , viscosity , chemistry , crystal structure , crystallography , organic chemistry , composite material
A linear supramolecular polymer based on the self‐assembly of an easily available copillar[5]arene monomer is efficiently prepared, which is evidenced by the NMR spectroscopy, viscosity measurement, and DOSY experiment. The single‐crystal X‐ray analysis reveals that the polymerization of the AB‐type monomer is driven by the quadruple CH•••π interactions and one CH•••O interaction.