Click Construction of Spiro‐ and Bridged‐Quatrefoil Polymer Topologies with Kyklo‐Telechelics Having an Azide Group | Zendy

Ko Yee Song | Zendy; Yamamoto Takuya | Zendy; Tezuka Yasuyuki | Zendy

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Click Construction of Spiro‐ and Bridged‐Quatrefoil Polymer Topologies with Kyklo‐Telechelics Having an Azide Group

Author(s) -

Ko Yee Song,

Yamamoto Takuya,

Tezuka Yasuyuki

Publication year - 2014

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.201300555

Subject(s) - azide , polymer science , click chemistry , group (periodic table) , polymer , polymer chemistry , materials science , chemistry , composite material , organic chemistry

Unprecedented tetracyclic polymer topologies with spiro‐ and a bridged‐type quatrefoil forms are effectively constructed through an alkyne‐azide, click‐linking reaction by employing a kyklo‐telechelic poly(tetrahydrofuran), poly(THF), precursor having an azide group, obtained through an electrostatic self‐assembly and covalent fixation (ESA‐CF) process, and complementary tetrafunctional alkyne reagents of either a pentaerythritol derivative or a four‐armed star telechelic polymer precursor.

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