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Fibrils Formed by Dendron‐ b ‐oligoaniline‐ b ‐dendron Block Co‐oligomer
Author(s) -
Xiong Wei,
Wang Hanfu,
Han Yanchun
Publication year - 2010
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.201000303
Subject(s) - oligomer , dendrimer , stacking , intermolecular force , micelle , fibril , materials science , amphiphile , quenching (fluorescence) , polymer chemistry , chemistry , crystallography , copolymer , molecule , fluorescence , polymer , organic chemistry , aqueous solution , composite material , quantum mechanics , biochemistry , physics
Novel dendritic triblock co‐oligomer (14G2A3) consisting of ester dendrons and aniline oligomer was synthesized and found to self‐assemble into fibrils in THF. Studies reveal that the formation of the fibrils originates from both of the amphiphilic interactions between the ester dendrons and oligoaniline, as well as the intermolecular π‐π stacking among oligoanilines. The shape effect of dendrons on molecular packing was comparatively analyzed with packing parameter against its linear analogous compound. At the same time, the driving forces that dominate the final aggregating state of the block oligomer were separately investigated using the bulky‐group protecting method, which allows release of the intermolecular π‐π stacking of oligoaniline in a controlled manner. Results show that both the introduction of dendrons and the intermolecular π‐π stacking will increase the packing parameter of the block oligomer and, consequently, cause the self‐assembly morphology to evolve step by step from micelles to vesicles and finally to fibrils. The fibrils can form complexes with SWNTs to increase solubility in THF. The effective fluorescence quenching accompanied also opens a gate for the block co‐oligomer to have potential applications in organic electronic devices.