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Precision Sulfonic Acid Ester Copolymers
Author(s) -
Opper Kathleen L.,
Wagener Kenneth B.
Publication year - 2009
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.200900013
Subject(s) - sulfonic acid , polymer chemistry , copolymer , polymer , materials science , condensation polymer , polyester , amorphous solid , glass transition , organic chemistry , chemistry
Linear ethylene copolymers containing sulfonic acid ethyl esters precisely spaced on every 21st carbon have been synthesized using metathesis polycondensation chemistry. These precision structures with one directly attached and one aromatic spaced sulfonic acid ester are synthesized with the goal of tailoring layered higher order morphologies in contrast to conventional clustered ionic polyolefins. Primary structural characterization confirms the precision polymer structures. Additional secondary microstructural analysis by DSC shows a recoverable endothermic melt transition of polyethylene‐like lamellae crystallites of the directly attached ester while completely amorphous behavior is observed when the ester is spaced away from the backbone with an aromatic group.