Macromol. Rapid Commun. 5/2007 | Zendy

Potemkin Igor I. | Zendy; Busch Peter | Zendy; Smilgies DetlefM. | Zendy; Posselt Dorthe | Zendy; Papadakis Christine M. | Zendy

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Macromol. Rapid Commun. 5/2007

Author(s) -

Potemkin Igor I.,

Busch Peter,

Smilgies DetlefM.,

Posselt Dorthe,

Papadakis Christine M.

Publication year - 2007

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200790009

Subject(s) - lamellar structure , copolymer , grazing incidence small angle scattering , materials science , molar mass , scattering , atomic force microscopy , anisotropy , polymer science , polymer chemistry , composite material , optics , crystallography , physics , chemistry , nanotechnology , polymer , neutron scattering , small angle neutron scattering

Cover: The article by Potemkin and coworkers provides free‐energy considerations to explain the molar mass dependent morphology of lamellar diblock copolymer thin films of poly(styrene‐ b ‐butadiene). Atomic force microscopy (AFM) and grazing‐incidence small‐angle scattering (GISAXS) data were instrumental to establish the lamellar orientation as a function of the interaction parameter χN and the ratio of film thickness over lamellar thickness D red . The relevant free‐energy contributions are discussed that determine the boundary between the observed orientational phases. Further details can be found in the article by I. I. Potemkin, * P. Busch, D.‐M. Smilgies, D. Posselt, and C. M. Papadakis on page 579.

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