Construction of a Hexameric Zn(II)‐metallomacrocycle and its Photo‐ and Electroluminescence Properties: [Zn 6 ( O ‐hexyl‐3,5‐bis(2,2′:6′,2″‐terpyridine)phenol) 6 (BF 4 ) 12 ] | Zendy

Hwang SeokHo | Zendy; Wang Pingshan | Zendy; Moorefield Charles N. | Zendy; Jung JaeChang | Zendy; Kim JeongYeol | Zendy; Lee SangWon | Zendy; Newkome George R. | Zendy

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Construction of a Hexameric Zn(II)‐metallomacrocycle and its Photo‐ and Electroluminescence Properties: [Zn 6 ( O ‐hexyl‐3,5‐bis(2,2′:6′,2″‐terpyridine)phenol) 6 (BF 4 ) 12 ]

Author(s) -

Hwang SeokHo,

Wang Pingshan,

Moorefield Charles N.,

Jung JaeChang,

Kim JeongYeol,

Lee SangWon,

Newkome George R.

Publication year - 2006

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200600516

Subject(s) - terpyridine , electroluminescence , materials science , photoluminescence , photochemistry , oled , ligand (biochemistry) , crystallography , chemistry , optoelectronics , metal , nanotechnology , biochemistry , receptor , layer (electronics) , metallurgy

Summary: An O ‐hexyl‐3,5‐bis(terpyridine)phenol ligand has been synthesized and transformed into a hexagonal Zn(II)‐metallomacrocycle by a facile self‐assembly procedure capitalizing on terpyridine‐Zn(II)‐terpyridine connectivity. The structural composition was confirmed by NMR and mass spectral techniques; photo‐ and electroluminescence properties were also investigated. The OLED device shows green electroluminescent emission at 515 nm with a maximum luminance of 39 cd · m −2 and maximum efficiency of 0.16 cd · A −1 .Structure and electroluminescent properties of the metallomacrocycle investigated.

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