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Surface Functionalization of Fe 3 O 4 Magnetic Nanoparticles via RAFT‐Mediated Graft Polymerization
Author(s) -
Wang WenCai,
Neoh KoonGee,
Kang EnTang
Publication year - 2006
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.200600409
Subject(s) - polystyrene , polymerization , chain transfer , surface modification , reversible addition−fragmentation chain transfer polymerization , polymer chemistry , materials science , raft , polymer , radical polymerization , styrene , acrylic acid , nanoparticle , gel permeation chromatography , fourier transform infrared spectroscopy , chemical engineering , copolymer , nanotechnology , engineering , composite material
Summary: Surface functionalization of Fe 3 O 4 magnetic nanoparticles (MNP) via living radical graft polymerization with styrene and acrylic acid (AAc) in the reversible addition‐fragmentation chain transfer (RAFT)‐mediated process was reported. Peroxides and hydroperoxides generated on the surface of Fe 3 O 4 nanoparticles via ozone pretreatment facilitated the thermally initiated graft polymerization in the RAFT‐mediated process. A comparison of the MNP before and after the RAFT‐mediated process was carried out using transmission electron microscopy (TEM) analysis, Fourier transform infrared (FTIR), and X‐ray photoelectron spectroscopy (XPS). Gel permeation chromatography (GPC) was used to determine the molecular weight of the free homopolymer in the reaction mixture. Well‐defined polymer chains were grown from the MNP surfaces to yield particles with a Fe 3 O 4 core and a polymer outer layer. The resulting core–shell Fe 3 O 4 ‐ g ‐polystyrene and Fe 3 O 4 ‐ g ‐poly(acrylic acid) (PAAc) nanoparticles formed stable dispersions in the organic solvents for polystyrene (PS) and PAAc, respectively.Schematic illustration of thermally induced graft polymerization of styrene and AAc with the ozone‐treated Fe 3 O 4 MNP.