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Thermoreversible Ferrogels
Author(s) -
Lattermann Günter,
Krekhova Marina
Publication year - 2006
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.200600284
Subject(s) - magnetite , ferrofluid , polystyrene , homogeneous , materials science , chemical engineering , phase (matter) , nanoparticle , polymer science , nanotechnology , polymer chemistry , composite material , chemistry , polymer , magnetic field , organic chemistry , physics , thermodynamics , quantum mechanics , engineering , metallurgy
Summary: For the first time, thermoreversible ferrogels (FG) by physical gelation of ferrofluids have been described. Finavestan A80B paraffin oil in a concentration range of the gelator KRATON G‐1650 with C gelator = 3–10 wt.‐%, was used to obtain stable and homogeneous FGs. TEM micrographs revealed that the magnetite particles are preferably located in the ‘free’ paraffin phase between micellar domains of the gelator. So, the magnetite nanoparticles make visible a ‘negative’ picture of the structure of the micellar domains of the gel, which is observed in the pure gel as a ‘positive’ image. The mean diameter of the polystyrene cores is $\overline d$ = 17 nm, and that of the magnetite particles is $\overline d$ = 7 nm.