Premium
Synthesis of Porous Polyurea with Room‐Temperature Ionic Liquids via Interfacial Polymerization
Author(s) -
Zhu Lining,
Huang ChienYueh,
Patel Yamini H.,
Wu Jing,
Malhotra Sanjay V.
Publication year - 2006
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.200600256
Subject(s) - polyurea , materials science , polymer , ionic liquid , scanning electron microscope , polymerization , chemical engineering , ionic bonding , porosity , morphology (biology) , micrograph , polymer chemistry , interfacial polymerization , composite material , chemistry , polyurethane , ion , organic chemistry , monomer , biology , engineering , genetics , catalysis
Summary: Polyurea with exotic porous structures has been synthesized by the interfacial polymerization between hexane and a series of 1‐alkyl‐3‐methylimidazolium room‐temperature ionic liquids (ILs). Scanning electron microscopy micrographs of the polyurea show a macroporous morphology of aggregated polymer particles with sizes around 200 nm and pore sizes between 100 to 500 nm. The geometry of the polymer particles and the pore size vary with the ILs employed. X‐Ray diffraction shows ionic‐liquid‐induced suppression of 3D crystalline order in the polyurea products. The microstructures of the polymer together with the FT‐IR results suggest that the observed exotic polymer morphology originates from interactions between the ionic liquid and the polymer.SEM micrograph of the interconnected macroporous structure of the polyurea formed in [C 2 mim][BF 4 ] ionic liquid. The scale bar is 100 nm.