Synthesis and Self‐Assembly of Amphiphilic Diblock Copolymers using a Fluorescently Labeled  N ‐Alkoxyamine Initiator | Zendy

Tsimelzon Anna | Zendy; Deamer David | Zendy; Braslau Rebecca | Zendy

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Synthesis and Self‐Assembly of Amphiphilic Diblock Copolymers using a Fluorescently Labeled N ‐Alkoxyamine Initiator

Author(s) -

Tsimelzon Anna,

Deamer David,

Braslau Rebecca

Publication year - 2005

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200500608

Subject(s) - copolymer , amphiphile , polymer chemistry , nitroxide mediated radical polymerization , radical polymerization , polystyrene , polymerization , alkyl , fluorescence , acrylic acid , materials science , chemistry , polymer , organic chemistry , physics , quantum mechanics

Summary: An initiator for nitroxide mediated ‘living’ free radical polymerization was prepared with a fluorescent tag attached to the initiating alkyl radical terminus. This was used to synthesize amphiphilic poly(acrylic acid)‐ block ‐polystyrene diblock copolymers, which self assembled in a tetrahydrofuran/buffer solution to form structures that are visible by fluorescence.

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