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Surface‐Initiated Atom Transfer Radical Polymerization of Oligo(ethylene glycol) Methacrylate: Effect of Solvent on Graft Density
Author(s) -
Feng Wei,
Chen Renxu,
Brash John L.,
Zhu Shiping
Publication year - 2005
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.200500335
Subject(s) - ethylene glycol , atom transfer radical polymerization , polymer chemistry , monomer , chemistry , methacrylate , materials science , polymer , organic chemistry
Summary: Oligo(ethylene glycol) methacrylate (OEGMA) was grafted from silicon wafer surfaces by surface‐initiated atom transfer radical polymerization (ATRP) with Cu I Br/2,2′‐bipyridine (bpy) as a catalyst and various water/alcohol mixtures as solvents. The ellipsometric thickness of the poly(OEGMA) layer on the surface increased linearly with monomer conversion in solution. High graft densities were achieved in alcohols. The graft density of poly(OEGMA) in methanol was found to be 0.26 chains · nm −2 , which is 50% higher than that in water/methanol (30:70, v/v). The differences in graft density were correlated to the conformation of tethered poly(OEGMA) chains. Large poly(OEGMA) coils on the surface in the presence of water limited the access of initiation sites to the catalyst complex and monomer molecules.Development of poly(OEGMA) layer thickness on the silicon surface vs monomer conversion.