A Closed‐Loop Phase Diagram in a Weakly Interacting Polyolefin Copolymer Binary Blend System | Zendy

Hu Haiqing | Zendy; Chong Chuanbo | Zendy; He Aihua | Zendy; Zhang Chenggui | Zendy; Fan Guoqiang | Zendy; Dong JinYong | Zendy; Han Charles C. | Zendy

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A Closed‐Loop Phase Diagram in a Weakly Interacting Polyolefin Copolymer Binary Blend System

Author(s) -

Hu Haiqing,

Chong Chuanbo,

He Aihua,

Zhang Chenggui,

Fan Guoqiang,

Dong JinYong,

Han Charles C.

Publication year - 2005

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200500182

Subject(s) - phase diagram , materials science , polyolefin , copolymer , phase (matter) , styrene , polymer blend , polymer chemistry , diagram , phase boundary , crystallization , thermodynamics , chemical engineering , polymer , composite material , chemistry , physics , organic chemistry , mathematics , statistics , layer (electronics) , engineering

Summary: The phase behavior of poly(ethylene‐ co ‐styrene) (PES) and poly(ethylene‐ co ‐butene) (PEB) blends has been studied. A closed‐loop phase diagram was clearly observed in this weakly interacting system as the styrene content in the PES decreased to about 1 mol‐%. At higher styrene contents, the phase loop starts to interplay with the crystallization transformation at lower temperatures.Phase diagram of PEB/PES blends. Phase boundary line is only for easy demonstration.

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