Aqueous RAFT Polymerization of Acrylamide and  N , N ‐Dimethylacrylamide at Room Temperature | Zendy

Convertine Anthony J. | Zendy; Lokitz Brad S. | Zendy; Lowe Andrew B. | Zendy; Scales Charles W. | Zendy; Myrick Leslie J. | Zendy; McCormick Charles L. | Zendy

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Aqueous RAFT Polymerization of Acrylamide and N , N ‐Dimethylacrylamide at Room Temperature

Author(s) -

Convertine Anthony J.,

Lokitz Brad S.,

Lowe Andrew B.,

Scales Charles W.,

Myrick Leslie J.,

McCormick Charles L.

Publication year - 2005

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200500042

Subject(s) - chain transfer , polymerization , raft , acrylamide , reversible addition−fragmentation chain transfer polymerization , polymer chemistry , aqueous solution , hydrolysis , chemistry , aqueous medium , polymer , radical polymerization , copolymer , organic chemistry

Summary: The first example of a room temperature reversible addition‐fragmentation chain transfer polymerization conducted directly in aqueous media is detailed. Under these conditions acrylamide and N , N ‐dimethylacrylamide may be polymerized in a controlled fashion to near quantitative conversions employing a difunctional trithiocarbonate chain transfer agent (CTA). Hydrolysis studies conducted at pH 5.5 suggest that the CTA is stable up to approximately 50 °C.

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