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Electroactive Shape‐Memory Polyurethane Composites Incorporating Carbon Nanotubes
Author(s) -
Cho Jae Whan,
Kim Jeong Won,
Jung Yong Chae,
Goo Nam Seo
Publication year - 2005
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.200400492
Subject(s) - materials science , composite material , polyurethane , carbon nanotube , shape memory alloy , elongation , surface energy , conductivity , modulus , ultimate tensile strength , chemistry
Summary: Electro‐active shape‐memory composites were synthesized using conducting polyurethane (PU) composites and multi‐walled carbon nanotubes (MWNTs). Surface modification of the MWNTs (by acid treatment) improved the mechanical properties of the composites. The modulus and stress at 100% elongation increased with increasing surface‐modified MWNT content, while elongation at break decreased. MWNT surface modification also resulted in a decrease in the electrical conductivity of the composites, however, as the surface modified MWNT content increased the conductivity increased (an order of 10 −3 S · cm −1 was obtained in samples with 5 wt.‐% modified‐MWNT content). Electro‐active shape recovery was observed for the surface‐modified MWNT composites with an energy conversion efficiency of 10.4%. Hence, PU‐MWNT composites may prove promising candidates for use as smart actuators.The electro‐active shape‐recovery behavior of PU‐MWNT composites. The pictured transition occurs within 10 s when a constant voltage of 40 V is applied.