β ‐Cyclodextrin Pseudopolyrotaxanes with  π ‐Conjugated Polymer Axles | Zendy

Yamaguchi Isao | Zendy; Kashiwagi Kohki | Zendy; Yamamoto Takakazu | Zendy

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β ‐Cyclodextrin Pseudopolyrotaxanes with π ‐Conjugated Polymer Axles

Author(s) -

Yamaguchi Isao,

Kashiwagi Kohki,

Yamamoto Takakazu

Publication year - 2004

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200400024

Subject(s) - cyclodextrin , inclusion (mineral) , thiophene , polymer , axle , chemistry , flexibility (engineering) , inclusion compound , conjugated system , polymer chemistry , organic chemistry , mineralogy , physics , mathematics , thermodynamics , statistics

Summary: β ‐Cyclodextrin ( β ‐CD) pseudopolyrotaxanes containing poly(thiophene‐2,5‐diyl), PTh , or poly(3‐methylthiophene‐2,5‐diyl)s, P3MeTh s, as an axle were prepared. Structures of the pseudopolyrotaxanes and their inclusion behavior with β ‐CD were investigated. The UV‐vis measurements revealed that inclusion of P3MeTh s by β ‐CD depended on the flexibility of the main chain and their molecular weight.Formation of the inclusion complex of β ‐CD and PTh .

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