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Automated Parallel Synthesis of MADIX (Co)Polymers
Author(s) -
Chapon Pascal,
Mignaud Catherine,
Lizarraga Gilda,
Destarac Mathias
Publication year - 2003
Publication title -
macromolecular rapid communications
Language(s) - English
Resource type - Journals
SCImago Journal Rank - 1.348
H-Index - 154
eISSN - 1521-3927
pISSN - 1022-1336
DOI - 10.1002/marc.200390016
Subject(s) - polymer , copolymer , characterization (materials science) , materials science , polymerization , polymer chemistry , computer science , nanotechnology , composite material
An automated parallel synthetic approach has been developed for synthesizing polymer libraries by the Macromolecular Design via the Interchange of Xanthates (MADIX) process. The experimental set‐up, parallel polymerizations, characterization, and reproducibility tests are detailed. Examples of acrylic diblock copolymers synthesized in this way are given.Automated MADIX polymerizations of BA in the presence of a X 1 ‐capped PEA.