Novel Chromophore‐Functionalized Poly[2‐(trifluoromethyl) adamantyl acrylate‐methyl vinyl urethane]s with High Poling Stabilities of the Nonlinear Optical Effect | Zendy

Briers David | Zendy; Koeckelberghs Guy | Zendy; Picard Isabel | Zendy; Verbiest Thierry | Zendy; Persoons André | Zendy; Samyn Celest | Zendy

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Novel Chromophore‐Functionalized Poly[2‐(trifluoromethyl) adamantyl acrylate‐methyl vinyl urethane]s with High Poling Stabilities of the Nonlinear Optical Effect

Author(s) -

Briers David,

Koeckelberghs Guy,

Picard Isabel,

Verbiest Thierry,

Persoons André,

Samyn Celest

Publication year - 2003

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200350029

Subject(s) - chromophore , materials science , polymer chemistry , methyl acrylate , thiophene , polymer , acceptor , glass transition , isocyanate , acrylate , photochemistry , trifluoromethyl , copolymer , surface modification , chemistry , organic chemistry , polyurethane , composite material , physics , alkyl , condensed matter physics

Nonlinear optical vinyl polymers with high glass transition temperature ( T g ) were prepared by the functionalization of a fluorinated acrylate‐methyl vinyl isocyanate copolymer. A modified pathway to obtain a thiophene bridged chromophore was worked out. Poled films of the polymers show a fairly high and stable nonlinear optical response, even at elevated temperatures.The thiophene‐bridged chromophore, based on a substituted dicyanomethylene‐dihydrofuran acceptor, synthesized here.

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