A Mixed Ruthenium Polypyridyl Complex Containing a PEG‐Bipyridine Macroligand | Zendy

Marin Veronica | Zendy; Holder Elisabeth | Zendy; Meier Michael A. R. | Zendy; Hoogenboom Richard | Zendy; Schubert Ulrich S. | Zendy

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A Mixed Ruthenium Polypyridyl Complex Containing a PEG‐Bipyridine Macroligand

Author(s) -

Marin Veronica,

Holder Elisabeth,

Meier Michael A. R.,

Hoogenboom Richard,

Schubert Ulrich S.

Publication year - 2004

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200300299

Subject(s) - ruthenium , bipyridine , ethylene glycol , polymer chemistry , peg ratio , polymer , materials science , chemistry , photochemistry , organic chemistry , catalysis , crystal structure , finance , economics

Summary: An amino‐functionalized bipyridine ligand was prepared in order to serve as a bridging unit to an activated low‐molecular‐weight monomethyl ether of poly(ethylene glycol) (PEG). Coordination of a ruthenium( II ) phenantroline precursor onto the formed PEG‐containing bipyridine ligand yielded a metal‐containing polymer which shows interesting properties for solar cell applications.A schematic of the described polymeric ruthenium( II ) complex and its absorption and emission properties.

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