Thin Films by Multilayer Build‐Up of Electron Transport Materials | Zendy

Mruk Ralf | Zendy; Prehl Sabine | Zendy; Zentel Rudolf | Zendy

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Thin Films by Multilayer Build‐Up of Electron Transport Materials

Author(s) -

Mruk Ralf,

Prehl Sabine,

Zentel Rudolf

Publication year - 2003

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200300053

Subject(s) - schematic , materials science , electron transport chain , condensation polymer , polyelectrolyte , electrochemistry , electron , diagram , chemical engineering , triazine , nanotechnology , polymer chemistry , polymer , electrode , composite material , chemistry , computer science , physics , quantum mechanics , electronic engineering , engineering , database , biochemistry

We present the synthesis and the electrochemical characterization of polymeric electron transport materials, synthesized by polycondensation of substituted triazines and α , ω ‐dihaloalkanes. They can be reversibly reduced with the least negative potential at −0.39 V, which is below the reduction potential of oxygen. In addition, the formation of polyelectrolyte multilayers is possible by the electrostatic self‐assembly method. This multilayer formation takes place in a very defined way up to thirty double layers.An example of one of the polymeric triazine electron transport materials synthesized and a schematic diagram of a self‐assembled multilayer film.

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