Propylene Polymerization with Bis(phenoxy‐imine) Group‐4 Catalysts Using   i  Bu 3 Al/Ph 3 CB(C 6 F 5 ) 4  as a Cocatalyst | Zendy

Saito Junji | Zendy; Onda Mitsuhiko | Zendy; Matsui Shigekazu | Zendy; Mitani Makoto | Zendy; Furuyama Rieko | Zendy; Tanaka Hidetsugu | Zendy; Fujita Terunori | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Propylene Polymerization with Bis(phenoxy‐imine) Group‐4 Catalysts Using i Bu 3 Al/Ph 3 CB(C 6 F 5 ) 4 as a Cocatalyst

Author(s) -

Saito Junji,

Onda Mitsuhiko,

Matsui Shigekazu,

Mitani Makoto,

Furuyama Rieko,

Tanaka Hidetsugu,

Fujita Terunori

Publication year - 2003

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.200290005

Subject(s) - tacticity , polymerization , polymer chemistry , catalysis , imine , materials science , melting point , crystallography , polymer , chemistry , organic chemistry , composite material

The catalytic behavior of three bis(phenoxy‐imine) group‐4 transition‐metal complexes (M = Ti, Zr, Hf), with i Bu 3 Al/Ph 3 CB(C 6 F 5 ) 4 cocatalyst systems towards propylene polymerization was investigated under atmospheric pressure at 25 °C. The Ti complex produced ultrahigh‐molecular‐weight atactic poly(propylene), whereas Zr and Hf complexes formed high‐molecular‐weight isotactic poly(propylene)s via a site‐control mechanism. The isotactic poly(propylene) obtained with the Hf complex displayed a high melting temperature of 123.8 °C.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research