Polymerization of 1‐vinylcyclohexene in the presence of group 4 metallocenes – MAO catalysts | Zendy

Longo Pasquale | Zendy; Grassi Alfonso | Zendy; Grisi Fabia | Zendy; Milione Stefano | Zendy

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Polymerization of 1‐vinylcyclohexene in the presence of group 4 metallocenes – MAO catalysts

Author(s) -

Longo Pasquale,

Grassi Alfonso,

Grisi Fabia,

Milione Stefano

Publication year - 1998

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1998.030190501

Subject(s) - methylaluminoxane , cyclopentadienyl complex , tacticity , metallocene , polymerization , isopropyl , polymer chemistry , catalysis , polymer , chemistry , materials science , organic chemistry

1‐Vinylcyclohexene was polymerized in the presence of several homogeneous catalytic systems consisting of methylaluminoxane and group 4 metallocenes such as CpTiCl 3 , [isopropyl(cyclopentadienyl)(1‐fluorenyl)]ZrCl 2 , rac ‐[ethylenebis(1‐indenyl)] ZrCl 2 , (CH 3 ) 2 Si(Cp) 2 ZrCl 2 , CpZrCl 3 . The structure of the polymers depends on the catalyst. In fact, with CpTiCl 3 , [isopropyl(cyclopentadienyl)(1‐fluorenyl)]ZrCl 2 and rac ‐[ethylenebis‐(1‐indenyl)]ZrCl 2 the polymers are chemo‐, regio‐ and stereoregular with 1,4 cis , 1,4 trans and 1,2 isotactic structure, respectively.

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