Preparation of amphiphilic networks by Diels‐Alder reactions between oligo(butyl methacrylate) with furan end‐groups and a poly(ethylene oxide‐ co ‐acetylenedicarboxylate) | Zendy

Delerba Mark | Zendy; Ebdon John R. | Zendy; Rimmer Stephen | Zendy

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Preparation of amphiphilic networks by Diels‐Alder reactions between oligo(butyl methacrylate) with furan end‐groups and a poly(ethylene oxide‐ co ‐acetylenedicarboxylate)

Author(s) -

Delerba Mark,

Ebdon John R.,

Rimmer Stephen

Publication year - 1997

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1997.030180814

Subject(s) - acetylenedicarboxylate , furan , ethylene oxide , dimethyl acetylenedicarboxylate , amphiphile , polymer chemistry , organic chemistry , end group , diels–alder reaction , methacrylate , chemistry , materials science , copolymer , cycloaddition , polymer , catalysis

A butyl methacrylate oligomer with furan end‐groups was synthesized by ozonolysing a poly(butyl methacrylate‐ co ‐butadiene) latex. The end‐groups of this oligomer were amidated with aminomethylfuran to give a coagulated mass of derivatized oligomers. This furan functional oligomer was then mixed with poly(ethylene oxide‐ co ‐acetylenedicarboxylate) and heated at 60°C or 125°C. The material cured at 125°C was found to contain a higher gel fraction (55 wt.‐%) than that cured at 60°C (30 wt.‐%).

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