Ethylene polymerizations with novel tantalum(V) aminopyridinato complex/MAO systems | Zendy

Hakala Kimmo | Zendy; Löfgren Barbro | Zendy; Polamo Mika | Zendy; Leskelä Markku | Zendy

AI Assistant Blog Pricing

Home ZAIA Blog

Premium

Ethylene polymerizations with novel tantalum(V) aminopyridinato complex/MAO systems

Author(s) -

Hakala Kimmo,

Löfgren Barbro,

Polamo Mika,

Leskelä Markku

Publication year - 1997

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1997.030180802

Subject(s) - tantalum , materials science , ethylene , polymer chemistry , polymer science , chemistry , organic chemistry , catalysis , metallurgy

The use of two kinds of tantalum(V) aminopyridinato complexes, bis(2‐benzylaminopyridinato)trichlorotantalum(V) and trichlorobis[2,6‐di(phenylamino)pyridinato‐ N , N ′]‐tantalum(V), activated by methylaluminoxane was studied in polymerization of ethylene. The activities of these homogeneous catalyst systems are comparable to those of metallocenes. The weight‐average molecular weights ( M̄ w ) of the produced polyethylenes are between 60 000 and 200 000 and M̄ w / M̄ n ≈ 2.

This content is not available in your region!

Continue researching here.

Having issues? You can contact us here

Accelerating Research