13 C‐enriched end groups of poly(3,7‐dimethyl‐1‐octene) prepared in the presence of isotactic specific catalysts | Zendy

Longo Pasquale | Zendy; Oliva Patrizia | Zendy; Oliva Leone | Zendy

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13 C‐enriched end groups of poly(3,7‐dimethyl‐1‐octene) prepared in the presence of isotactic specific catalysts

Author(s) -

Longo Pasquale,

Oliva Patrizia,

Oliva Leone

Publication year - 1997

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1997.030180606

Subject(s) - tacticity , stereospecificity , homogeneous , catalysis , stereoselectivity , 1 octene , octene , materials science , copolymer , polymer chemistry , polymerization , chemistry , organic chemistry , polymer , combinatorics , mathematics , ethylene

Polymerizations of ( R , S )‐3,7‐dimethyl‐1‐octene in the presence of heterogeneous or homogeneous isotactic specific catalysts give very similar products with a homopolymeric isotactic structure. The insertion of ( R , S )‐3,7‐dimethyl‐1‐octene into the metal‐CH 3 bond (both heterogeneous and homogeneous catalysts) is highly stereospecific and stereoselective.

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