Synthesis of polysilanes by reductive coupling of dichlorosilanes mediated with alkali metal/crown ether supramolecular complexes in a homogeneous system | Zendy

Jedliński Zbigniew J. | Zendy; Kurcok Piotr | Zendy; Nozirow Farhod | Zendy

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Synthesis of polysilanes by reductive coupling of dichlorosilanes mediated with alkali metal/crown ether supramolecular complexes in a homogeneous system

Author(s) -

Jedliński Zbigniew J.,

Kurcok Piotr,

Nozirow Farhod

Publication year - 1997

Publication title -

macromolecular rapid communications

Language(s) - English

Resource type - Journals

SCImago Journal Rank - 1.348

H-Index - 154

eISSN - 1521-3927

pISSN - 1022-1336

DOI - 10.1002/marc.1997.030180605

Subject(s) - crown ether , alkali metal , supramolecular chemistry , polymer chemistry , polysilane , halide , polymer , metal , materials science , molar mass distribution , supramolecular polymers , chemistry , molecule , organic chemistry , ion

Structure and properties of poly(methylphenylsilane) synthesized by reductive coupling of silyl halides with alkali metal supramolecular complexes: (Mt + /18‐crown‐6, Mt − , where Mt = K, Na; 18‐crown‐6 = 1,4,7,10,13,16‐hexaoxacyclooctadecane) were investigated. The coupling process yields polymers exhibiting narrow molecular weight distribution and number‐average molecular weights up to 8 500, cyclic oligomers being formed along with linear ones.

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