Preparation of a uniform poly(methyl methacrylate) macromonomer and its polymerization

Syndiotactic poly(methyl methacrylate) (st‐PMMA) macromonomer having methacryloyl end group was prepared from st‐PMMA living anion and separated into uniform macromonomers by means of supercritical fluid chromatography. A uniform macromonomer with the degree of polymerization of 32 was polymerized radically in benzene at 60°C. The uniform dimer, trimer and tetramer of the uniform macromonomer were isolated from the polymerization product by means of gel‐permeation chromatography (GPC). The intrinsic viscosity ([η]) in tetrahydrofuran of these uniform comblike polymers was determined by GPC/differential viscometric analysis. The plot of logarithmic [η] against logarithmic molecular weight indicated that the trimer and tetramer assume a little shrinking molecular shape as compared with the unimer and dimer.